Let $G$ be a finite simple non-complete connected graph on $[n] = \{1, \ldots, n\}$ and $κ(G) \geq 1$ its vertex connectivity. Let $f(G)$ denote the number of free vertices of $G$ and $\mathrm{diam}(G)$ the diameter of $G$. The final goal of this paper is to determine all sequences of integers $(n,f,d,k)$ with $n\geq 8$, $f\geq 0$, $d\geq 2$ and $k\geq 1$ for which there exists a finite simple non-complete connected graph on $[n]$ with $f=f(G)$, $d=\mathrm{diam}(G)$ and $k=κ(G)$.