This paper serves as the first extension of the topic of dominator colorings of graphs to the setting of digraphs. We establish the dominator chromatic number over all possible orientations of paths and cycles. In this endeavor we discover that there are infinitely many counterexamples of a graph and subgraph pair for which the subgraph has a larger dominator chromatic number than the larger graph into which it embeds. Finally, a new graph invariant measuring the difference between the dominator chromatic number of a graph and the chromatic number of that graph is established and studied. The paper concludes with some of the possible avenues for extending this line of research.