We define a cap in the affine geometry AG(n,2) to be a subset in which every collection of four points is in general position. In this paper, we classify, up to affine equivalence, all caps in AG(7,2) of size k greater than or equal to 10. In particular, we show that there are two equivalence classes of 10-caps and one equivalence class of 11-caps, none of which are complete, and one equivalence class of 12-caps, which are both complete and of maximum size.