The perfect matching complex of a simple graph $G$ is a simplicial complex having facets (maximal faces) as the perfect matchings of $G$. This article discusses the perfect matching complex of polygonal line tilings and the $\left(2 \times n\right)$-grid graph in particular. We use tools from discrete Morse theory to show that the perfect matching complex of any polygonal line tiling is either contractible or homotopy equivalent to a wedge of spheres. While proving our results, we also characterize all the matchings of $\left(2 \times n\right)$-grid graph that cannot be extended to form a perfect matching.