The HVN is a graph formed by removing two edges incident to the same vertex from the complete graph $K_5$. In this paper, we prove that every ($P_2\cup P_4$, HVN)-free graph $G$ satisfies $χ(G)\leq\lceil\frac{4}{3}ω(G)\rceil$ when $ω(G)\ge4$, where $χ(G)$ and $ω(G)$ denote the chromatic number and clique number of $G$, respectively. Furthermore, this bound is optimal for every $ω(G)\ge4$. Constructions demonstrating the optimality of the bound are provided. Our work unifies several previously known results on $χ$-binding functions for several graph classes.