We study the equivalence between bipartiteness and symmetry of spectra of mixed graphs, for $θ$-Hermitian adjacency matrices defined by an angle $θ\in (0, π]$. We show that this equivalence holds when, for example, an angle $θ$ is an algebraic number, while it breaks down for any angle $θ\in \mathbb{Q}π$. Furthermore, we construct a family of non-bipartite mixed graphs having the symmetric spectra for given $θ\in \mathbb{Q}π$.