We present a new cryptomorphic definition of orthogonal matroids with coefficients using Grassmann--Plücker functions. The equivalence is motivated by Cayley's identities expressing principal and almost-principal minors of a skew-symmetric matrix in terms of its Pfaffians. As a corollary of the new cryptomorphism, we deduce that each component of the orthogonal Grassmannian is parameterized by certain part of the Plücker coordinates.