We study P-groupoids that arise from certain decompositions of complete graphs. We show that left distributive P-groupoids are distributive, quasigroups. We characterize P-groupoids when the corresponding decomposition is a Hamiltonian decomposition for complete graphs of odd, prime order. We also study a specific example of a P-quasigroup constructed from cyclic groups of odd order. We show such P-quasigroups have characteristic left and right multiplication groups, as well as the right multiplication group is isomorphic to the dihedral group.