We present new pivot rules for the Simplex method for LPs over 0/1 polytopes. We show that the number of non-degenerate steps taken using these rules is strongly polynomial and even linear in the dimension or in the number of variables. Our bounds on the number of steps are asymptotically optimal on several well-known combinatorial polytopes. Our analysis is based on the geometry of 0/1 polytopes and novel modifications to the classical Steepest-Edge and Shadow-Vertex pivot rules. We draw interesting connections between our pivot rules and other well-known algorithms in combinatorial optimization.