Luis Ferroni and Alex Fink recently introduced a polytope of all unlabeled matroids of rank $r$ on $n$ elements, and they showed that the vertices of this polytope come from matroids that can be characterized by maximizing a sequence of valuative invariants. We prove that a number of the matroids that they conjectured to yield vertices indeed do (these include cycle matroids of complete graphs, projective geometries, and Dowling geometries), and we give additional examples (including truncations of cycle matroids of complete graphs, Bose-Burton geometries, and binary and free spikes with tips). We prove a special case of a conjecture of Ferroni and Fink by showing that direct sums of uniform matroids yield vertices of their polytope, and we prove a similar result for direct sums whose components are in certain restricted classes of extremal matroids.