For a graph $G$, let $\mathcal{S}(G)$ be the set consisting of Hermitian matrices whose graph is $G$. Denoted by $m_B(G,λ)$ the multiplicity of an eigenvalue $λ$ of $B(G)\in \mathcal{S}(G)$, we show that $m_B(G,λ)\le 2θ(G)+p(G)$ where $θ(G)$ and $p(G)$ are the cyclomatic number and the number of pendent vertices of $G$ respectively, and characterize the graphs attaining the equality. This is a generalization of a result on adjacency matrix by Wang et al.\cite{Wang1}. Moreover, they arose an open problem in \cite{Wang1}: \textit{characterize all graphs with $m_A(G,λ)=2θ(G)+p(G)-1$ for any eigenvalue $λ$ of its adjacency matrix.} In this paper, we completely characterize the graphs with $m_B(G,λ)=2θ(G)+p(G)-1$ for any eigenvalue $λ$ of an arbitrary Hermitian matrix $B(G)\in \mathcal{S}(G)$. This result provides a stronger answer to the above problem, and encompasses some previous known works considering $λ=-1$ or $0$ on the problem.