We study the minimum rank of a (simple, undirected) graph, which is the minimum rank among all matrices in a space determined by the graph. We determine the exact set of graphs on eight vertices for which the nullity of a minimum rank matrix does not coincide with a bound determined by the zero forcing number of a graph. Although our goal was to determine which eight-vertex graphs satisfy maximum nullity equal to the zero forcing number, we also established several additional methods to assist in the computation of minimum rank for general graphs.