Ribbon decomposition matrices give determinantal formulas for skew Schur functions that include as special cases the classical Jacobi-Trudi, Giambelli, and Lascoux-Pragacz formulas. We prove that certain elements of Lusztig's dual canonical basis, called Temperley-Lieb immanants, are Schur-positive when evaluated on ribbon decomposition matrices. We conjecture that this positivity holds for all elements of the dual canonical basis. This is known in the special case of Jacobi-Trudi matrices by a result of Haiman.