A caterpillar tree is a connected, acyclic, graph in which all vertices are either a member of a central path, or joined to that central path by a single edge. In other words, caterpillar trees are the class of trees which become path graphs after removing all leaves. In 1973, F. Harary and A.J. Schwenk provided two proofs found in [1] which show that the number of non-isomorphic caterpillars with N vertices is given by the formula $2^{N-4} + \ 2^{ \lfloor \frac{N - 4}{2}\rfloor}$, where $\lfloor \ \rfloor$ denotes the floor function. The first proof follows from a special case of an application of Pólya's Enumeration theorem on graphs with integer-weighted vertices. The second proof proceeds through an appropriate edge labelling of the caterpillars. The proof presented here owes much of its insight to the first two, but has the benefit of utilizing a natural labelling for the caterpillars. We will proceed by labelling the vertices of the caterpillars with integer-weights, followed by an application of the orbit-counting theorem.