In this article, we study degree one Cameron-Liebler sets of generators in all finite classical polar spaces, which is a particular type of a Cameron-Liebler set of generators in this polar space, [9]. These degree one Cameron-Liebler sets are defined similar to the Boolean degree one functions, [15]. We summarize the equivalent definitions for these sets and give a classification result for the degree one Cameron-Liebler sets in the polar spaces W(5,q) and Q(6,q).