For any finite connected poset $P$, Galashin introduced a simple convex $(|P|-2)$-dimensional polytope $\mathscr{A}(P)$ called the poset associahedron. For a certain family of posets, whose poset associahedra interpolate between the classical permutohedron and associahedron, we give a simple combinatorial interpretation of the $h$-vector. Our interpretation relates to the theory of stack-sorting of permutations. It also allows us to prove real-rootedness of some of their $h$-polynomials.