How can a stack of identical blocks be arranged to extend beyond the edge of a table as far as possible? We consider a generalization of this classic puzzle to blocks that differ in width and mass. Despite the seemingly simple premise, we demonstrate that it is unlikely that one can efficiently determine a stack configuration of maximum overhang. Formally, we prove that the Block-Stacking Problem is NP-hard, partially answering an open question from the literature. Furthermore, we demonstrate that the restriction to stacks without counterweights has a surprising connection to the Airplane Refueling Problem, another famous puzzle, and to Robust Appointment Scheduling, a problem of practical relevance. In addition to revealing a remarkable relation to the real-world challenge of devising schedules under uncertainty, their equivalence unveils a polynomial-time approximation scheme, that is, a $(1+ε)$-approximation algorithm, for Block Stacking without counterbalancing and a $(2+ε)$-approximation algorithm for the general case.