We prove that the set of matchings with a fixed number of unmatched vertices is Schur-positive with respect to the set of short chords. Two proofs are presented. The first proof applies a new combinatorial criterion for Schur-positivity, while the second is bijective. The coefficients in the Schur expansion are derived, and interpreted in terms of Bessel polynomials. We present a Knuth-like equivalence relation on matchings, and show that every equivalence class corresponds to an irreducible representation. We proceed to find various refined Schur-positive sets, including the set of matchings with a prescribed crossing number and the set of matchings with a given number of pairs of intersecting chords. Finally, we characterize all the matchings $m$ such that the set of matchings avoiding $m$ is Schur-positive.