We revisit the concepts of acyclic orderings and number of acyclic orderings of acyclic digraphs in terms of dispositions and counters for arbitrary multidigraphs. We prove that when we add a sequence of nested directed paths to a directed graph there is a unique polynomial such that the generatrix function of the family of counters is the product of the polynomial and the exponential function. We give an application, by considering a kind of digraphs arranged in rows introduced by the authors in a previous paper, called dispositional digraphs, in the particular case in which the digraph has two rows, to obtain new families of linear differential equations of small order whose coefficients are polynomials of small degree which admit polynomial solutions. In particular, we obtain a new differential equation associated to Catalan numbers, and the corresponding associated polynomials, which are solution of this differential equation; we term them Catalan differencial equation and Catalan polynomials, respectively. We prove that the Catalan polynomials obtained when we connect the directed path to the second vertex of the lower row of the digraph are orthogonal polynomials for an appropriate weight function. We characterize the digraphs that maximize the counter of connected dispositional digraphs and we find a new differential equation associated to these digraphs. We introduce also dispositions and counters in any multidigraph with non-strict inequalities in the dispositions, and we find new differential equations associated to some of them.