A linear Diophantine equation $ax + by = n$ is solvable if and only if gcd$(a; b)$ divides $n$. A graph $G$ of order $n$ is called Diophantine if there exists a labeling function $f$ of vertices such that gcd$(f(u); f(v))$ divides $n$ for every two adjacent vertices $u; v$ in $G$. In this work, maximal Diophantine graphs on $n$ vertices, $D_n$, are defined, studied and generalized. The independence number, the number of vertices with full degree and the clique number of $D_n$ are computed. Each of these quantities is the basis of a necessary condition for the existence of such a labeling.