A 3-dimensional Catalan word is a word on three letters so that the subword on any two letters is a Dyck path. For a given Dyck path $D$, a recently defined statistic counts the number of Catalan words with the property that any subword on two letters is exactly $D$. In this paper, we enumerate Dyck paths with this statistic equal to certain values, including all primes. The formulas obtained are in terms of Motzkin numbers and Motzkin ballot numbers.