We answer a question of Bergeron, Hohlweg, Rosas, and Zabrocki from 2006 to give a combinatorial description for the coproduct of the x-basis in the Hopf algebra of symmetric functions in noncommuting variables, NCSym, which arises in the theory of Grothendieck bialgebras. We achieve this using the theory of Hopf monoids and the Fock functor. We also determine combinatorial expansions of this basis in terms of the monomial and power sum symmetric functions in NCSym, and by taking the commutative image of the x-basis we discover a new multiplicative basis for the algebra of symmetric functions.