Motivated by the Saxl conjecture and the tensor square conjecture, which states that the tensor squares of certain irreducible representations of the symmetric group contain all irreducible representations, we study the tensor squares of irreducible representations associated with square Young diagrams. We give a formula for computing Kronecker coefficients, which are indexed by two square partitions and a three-row partition, specifically one with a short second row and the smallest part equal to 1. We also prove the positivity of square Kronecker coefficients for particular families of partitions, including three-row partitions and near-hooks.