The union vertex-distinguishing chromatic index $χ'_\cup(G)$ of a graph $G$ is the smallest natural number $k$ such that the edges of $G$ can be assigned nonempty subsets of $[k]$ so that the union of the subsets assigned to the edges incident to each vertex is different. We prove that $χ'_\cup(G) \in \left\{ \left\lceil \log_2\left(n +1\right) \right\rceil, \left\lceil \log_2\left(n +1\right) \right\rceil+1 \right\}$ for a graph $G$ on $n$ vertices without a component of order at most two. This answers a question posed by Bousquet, Dailly, Duchêne, Kheddouci and Parreau, and independently by Chartrand, Hallas and Zhang.