This is the second of a series of papers which aim towards a classification of edge-transitive maps of which the Euler characteristic and the edge number are coprime. This one carries out the classification work for arc-transitive maps with non-solvable automorphism groups, which together with the first one completes a description of arc-transitive maps with the Euler characteristic and the edge number coprime. The classification is involved with a construction of some new and interesting reversing maps.