Let G be a vertex-colored graph. We call a vertex cut S of G a monochromatic vertex cut if the vertices of S are colored with the same color. The graph G is monochromatically vertex-disconnected if any two nonadjacent vertices of G has a monochromatic vertex cut separating them. The monochromatic vertex-disconnection number of G, denoted by mvd(G), is the maximum number of colors that are used to make G monochromatically vertex-disconnected. In this paper, we propose an algorithm to compute mvd(G) and give an mvd-coloring of the graph G. We run this algorithm with an example written in Java. The main part of the code is shown in Appendix B and the complete code is given on Github: https://github.com/fumiaoT/mvd-coloring.git. Secondly, inspired by the previous localization principle, we obtain a upper bound of mvd(G) for some special classes of graphs. In addition, when mvd(G) is large and all blocks of G are minimally 2-connected triangle-free graphs, we characterize G. On these bases, we show that any graph whose blocks are all minimally 2-connected graphs of small order, can be computed mvd(G) and given an mvd-coloring in polynomial time.