A net occurrence of a repeated string in a text is an occurrence with unique left and right extensions, and the net frequency of the string is the number of its net occurrences in the text. Originally introduced for applications in Natural Language Processing, net frequency has recently gained attention for its algorithmic aspects. Guo et al. [CPM 2024] and Ohlebusch et al. [SPIRE 2024] focus on its computation in the offline setting, while Guo et al. [SPIRE 2024], Inenaga [arXiv 2024], and Mieno and Inenaga [CPM 2025] tackle the online counterpart. Mieno and Inenaga also characterize net occurrences in terms of the minimal unique substrings of the text. Additionally, Guo et al. [CPM 2024] initiate the study of net occurrences in Fibonacci words to establish a lower bound on the asymptotic running time of algorithms. Although there has been notable progress in algorithmic developments and some initial combinatorial insights, the combinatorial aspects of net occurrences have yet to be thoroughly examined. In this work, we make two key contributions. First, we confirm the conjecture that each Fibonacci word contains exactly three net occurrences. Second, we show that each Thue-Morse word contains exactly nine net occurrences. To achieve these results, we introduce the notion of overlapping net occurrence cover, which narrows down the candidate net occurrences in any text. Furthermore, we provide a precise characterization of occurrences of Fibonacci and Thue-Morse words of smaller order, offering structural insights that may have independent interest and potential applications in algorithm analysis and combinatorial properties of these words.