Causal discovery aims to recover ``what causes what'', but classical constraint-based methods (e.g., PC, FCI) suffer from error propagation, and recent LLM-based causal oracles often behave as opaque, confidence-free black boxes. This paper introduces Tree-Query, a tree-structured, multi-expert LLM framework that reduces pairwise causal discovery to a short sequence of queries about backdoor paths, (in)dependence, latent confounding, and causal direction, yielding interpretable judgments with robustness-aware confidence scores. Theoretical guarantees are provided for asymptotic identifiability of four pairwise relations. On data-free benchmarks derived from Mooij et al. and UCI causal graphs, Tree-Query improves structural metrics over direct LLM baselines, and a diet--weight case study illustrates confounder screening and stable, high-confidence causal conclusions. Tree-Query thus offers a principled way to obtain data-free causal priors from LLMs that can complement downstream data-driven causal discovery. Code is available at https://anonymous.4open.science/r/Repo-9B3E-4F96.