For min-max optimization and variational inequalities problems (VIP) encountered in diverse machine learning tasks, Stochastic Extragradient (SEG) and Stochastic Gradient Descent Ascent (SGDA) have emerged as preeminent algorithms. Constant step-size variants of SEG/SGDA have gained popularity, with appealing benefits such as easy tuning and rapid forgiveness of initial conditions, but their convergence behaviors are more complicated even in rudimentary bilinear models. Our work endeavors to elucidate and quantify the probabilistic structures intrinsic to these algorithms. By recasting the constant step-size SEG/SGDA as time-homogeneous Markov Chains, we establish a first-of-its-kind Law of Large Numbers and a Central Limit Theorem, demonstrating that the average iterate is asymptotically normal with a unique invariant distribution for an extensive range of monotone and non-monotone VIPs. Specializing to convex-concave min-max optimization, we characterize the relationship between the step-size and the induced bias with respect to the Von-Neumann's value. Finally, we establish that Richardson-Romberg extrapolation can improve proximity of the average iterate to the global solution for VIPs. Our probabilistic analysis, underpinned by experiments corroborating our theoretical discoveries, harnesses techniques from optimization, Markov chains, and operator theory.