Flow Matching (FM) (also referred to as stochastic interpolants or rectified flows) stands out as a class of generative models that aims to bridge in finite time the target distribution $ν^\star$ with an auxiliary distribution $μ$, leveraging a fixed coupling $π$ and a bridge which can either be deterministic or stochastic. These two ingredients define a path measure which can then be approximated by learning the drift of its Markovian projection. The main contribution of this paper is to provide relatively mild assumptions on $ν^\star$, $μ$ and $π$ to obtain non-asymptotics guarantees for Diffusion Flow Matching (DFM) models using as bridge the conditional distribution associated with the Brownian motion. More precisely, we establish bounds on the Kullback-Leibler divergence between the target distribution and the one generated by such DFM models under moment conditions on the score of $ν^\star$, $μ$ and $π$, and a standard $L^2$-drift-approximation error assumption.