Imbalanced classification often causes standard training procedures to prioritize the majority class and perform poorly on rare but important cases. A classic and widely used remedy is to augment the minority class with synthetic samples, but two basic questions remain under-resolved: when does synthetic augmentation actually help, and how many synthetic samples should be generated? We develop a unified statistical framework for synthetic augmentation in imbalanced learning, studying models trained on imbalanced data augmented with synthetic minority samples. Our theory shows that synthetic data is not always beneficial. In a "local symmetry" regime, imbalance is not the dominant source of error, so adding synthetic samples cannot improve learning rates and can even degrade performance by amplifying generator mismatch. When augmentation can help ("local asymmetry"), the optimal synthetic size depends on generator accuracy and on whether the generator's residual mismatch is directionally aligned with the intrinsic majority-minority shift. This structure can make the best synthetic size deviate from naive full balancing. Practically, we recommend Validation-Tuned Synthetic Size (VTSS): select the synthetic size by minimizing balanced validation loss over a range centered near the fully balanced baseline, while allowing meaningful departures. Extensive simulations and real data analysis further support our findings.