The increasing complexity and interconnectedness of systems across various fields have led to a growing interest in studying complex networks, particularly Scale-Free (SF) networks, which best model real-world systems. This paper investigates the influence of clustering on the observability and controllability of complex SF networks, framing these characteristics in the context of structured systems theory. In this paper, we show that densely clustered networks require fewer driver and observer nodes due to better information propagation within clusters. This relationship is of interest for optimizing network design in applications such as social networks and intelligent transportation systems. We first quantify the network observability/controllability requirements, and then, through Monte-Carlo simulations and different case studies, we show how clustering affects these metrics. Our findings offer practical insights into reducing control and observer nodes for sensor/actuator placement, particularly in resource-constrained setups. This work contributes to the understanding of network observability/controllability and presents techniques for improving these features through alterations in network structure and clustering.