Tensor Kronecker products, the natural generalization of the matrix Kronecker product, are independently emerging in multiple research communities. Like their matrix counterpart, the tensor generalization gives structure for implicit multiplication and factorization theorems. We present a theorem that decouples the dominant eigenvectors of tensor Kronecker products, which is a rare generalization from matrix theory to tensor eigenvectors. This theorem implies low rank structure ought to be present in the iterates of tensor power methods on Kronecker products. We investigate low rank structure in the network alignment algorithm TAME, a power method heuristic. Using the low rank structure directly or via a new heuristic embedding approach, we produce new algorithms which are faster while improving or maintaining accuracy, and scale to problems that cannot be realistically handled with existing techniques.