DevOps responds the growing need of companies to streamline the software development process and, thus, has experienced widespread adoption in the past years. However, the successful adoption of DevOps requires companies to address significant cultural and organizational changes. Understanding the organizational structure and characteristics of teams adopting DevOps is key, and comprehending the existing theories and representations of team taxonomies is critical to guide companies in a more systematic and structured DevOps adoption process. As there was no unified theory to explain the different topologies of DevOps teams, in previous work, we built a theory to represent the organizational structure and characteristics of teams adopting DevOps, harmonizing the existing knowledge. In this paper, we expand the theory-building in the context of DevOps Team Taxonomies. Our main contributions are presenting and executing the Operationalization and Testing phases for a continuously evolving theory on DevOps team structures. We operationalize the constructs and propositions that make up our theory to generate empirically testable hypotheses to confirm or disconfirm the theory. Specifically, we focus on the research operation side of the theory-research cycle: identifying propositions, deriving empirical indicators from constructs, establishing testable hypotheses, and testing them. We performed the operationalization and testing of the DevOps Team Taxonomies Theory, which resulted in an empirically verified and trustworthy theory. Our theory has 28 propositions representing this model that map properties to the constructs of our theory. The operationalization generated 34 testable hypotheses, and we thoroughly tested 11 of them. The testing has proved the effectiveness of the theoretical framework, while the operationalization of the constructs has enhanced the initial framework.