Reliably determining the performance of Retrieval-Augmented Generation (RAG) systems depends on comprehensive test questions. While a proliferation of evaluation frameworks for LLM-powered applications exists, current practices lack a systematic method to ensure these test sets adequately cover the underlying knowledge base, leaving developers with significant blind spots. To address this, we present a novel, applied methodology to quantify the semantic coverage of RAG test questions against their underlying documents. Our approach leverages existing technologies, including vector embeddings and clustering algorithms, to create a practical framework for validating test comprehensiveness. Our methodology embeds document chunks and test questions into a unified vector space, enabling the calculation of multiple coverage metrics: basic proximity, content-weighted coverage, and multi-topic question coverage. Furthermore, we incorporate outlier detection to filter irrelevant questions, allowing for the refinement of test sets. Experimental evidence from two distinct use cases demonstrates that our framework effectively quantifies test coverage, identifies specific content areas with inadequate representation, and provides concrete recommendations for generating new, high-value test questions. This work provides RAG developers with essential tools to build more robust test suites, thereby improving system reliability and extending to applications such as identifying misaligned documents.