Ethereum smart contracts hold tens of billions of USD in DeFi and NFTs, yet comprehensive security analysis remains difficult due to unverified code, proxy-based architectures, and the reliance on manual inspection of complex execution traces. Existing approaches fall into two main categories: anomaly transaction detection, which flags suspicious transactions but offers limited insight into specific attack strategies hidden in execution traces inside transactions, and code vulnerability detection, which cannot analyze unverified contracts and struggles to show how identified flaws are exploited in real incidents. As a result, analysts must still manually align transaction traces with contract code to reconstruct attack scenarios and conduct forensics. To address this gap, TraceLLM is proposed as a framework that leverages LLMs to integrate execution trace-level detection with decompiled contract code. We introduce a new anomaly execution path identification algorithm and an LLM-refined decompile tool to identify vulnerable functions and provide explicit attack paths to LLM. TraceLLM establishes the first benchmark for joint trace and contract code-driven security analysis. For comparison, proxy baselines are created by jointly transmitting the results of three representative code analysis along with raw traces to LLM. TraceLLM identifies attacker and victim addresses with 85.19\% precision and produces automated reports with 70.37\% factual precision across 27 cases with ground truth expert reports, achieving 25.93\% higher accuracy than the best baseline. Moreover, across 148 real-world Ethereum incidents, TraceLLM automatically generates reports with 66.22\% expert-verified accuracy, demonstrating strong generalizability.