Architectural Decision Records (ADRs) play a central role in maintaining software architecture quality, yet many decision violations go unnoticed because projects lack both systematic documentation and automated detection mechanisms. Recent advances in Large Language Models (LLMs) open up new possibilities for automating architectural reasoning at scale. We investigated how effectively LLMs can identify decision violations in open-source systems by examining their agreement, accuracy, and inherent limitations. Our study analyzed 980 ADRs across 109 GitHub repositories using a multi-model pipeline in which one LLM primary screens potential decision violations, and three additional LLMs independently validate the reasoning. We assessed agreement, accuracy, precision, and recall, and complemented the quantitative findings with expert evaluation. The models achieved substantial agreement and strong accuracy for explicit, code-inferable decisions. Accuracy falls short for implicit or deployment-oriented decisions that depend on deployment configuration or organizational knowledge. Therefore, LLMs can meaningfully support validation of architectural decision compliance; however, they are not yet replacing human expertise for decisions not focused on code.