Information asymmetry in financial markets, often amplified by strategically crafted corporate narratives, undermines the effectiveness of conventional textual analysis. We propose a novel multimodal framework for financial risk assessment that integrates textual sentiment with paralinguistic cues derived from executive vocal tract dynamics in earnings calls. Central to this framework is the Physics-Informed Acoustic Model (PIAM), which applies nonlinear acoustics to robustly extract emotional signatures from raw teleconference sound subject to distortions such as signal clipping. Both acoustic and textual emotional states are projected onto an interpretable three-dimensional Affective State Label (ASL) space-Tension, Stability, and Arousal. Using a dataset of 1,795 earnings calls (approximately 1,800 hours), we construct features capturing dynamic shifts in executive affect between scripted presentation and spontaneous Q&A exchanges. Our key finding reveals a pronounced divergence in predictive capacity: while multimodal features do not forecast directional stock returns, they explain up to 43.8% of the out-of-sample variance in 30-day realized volatility. Importantly, volatility predictions are strongly driven by emotional dynamics during executive transitions from scripted to spontaneous speech, particularly reduced textual stability and heightened acoustic instability from CFOs, and significant arousal variability from CEOs. An ablation study confirms that our multimodal approach substantially outperforms a financials-only baseline, underscoring the complementary contributions of acoustic and textual modalities. By decoding latent markers of uncertainty from verifiable biometric signals, our methodology provides investors and regulators a powerful tool for enhancing market interpretability and identifying hidden corporate uncertainty.