Large language model (LLM)-based text-to-speech (TTS) systems enable prompt-conditioned emotional control but struggle with fine-grained emotion intensity due to the semantic -- acoustic gap between text and speech. To address this challenge, we formulate emotion intensity control in LLM-based TTS as a learning-to-rank problem and propose Emo-LiPO, a listwise preference optimization framework that aligns prompt-conditioned speech generation with relative emotion intensity expressed in text. Emo-LiPO explicitly models global intensity ordering within each emotion under fixed transcripts, enabling more faithful and continuous emotional expression. We further construct ESD-plus, a multi-speaker dataset with explicit emotion intensity variations, to support fine-grained emotion modeling and evaluation. Experiments on ESD-plus demonstrate that Emo-LiPO significantly improves emotion accuracy and intensity controllability over both supervised- and DPO-based LLM TTS baselines, with particularly pronounced gains at high intensity levels.