The adaptivity and maneuvering capabilities of Autonomous Underwater Vehicles (AUVs) have drawn significant attention in oceanic research, due to the unpredictable disturbances and strong coupling among the AUV's degrees of freedom. In this paper, we developed large language model (LLM)-enhanced reinforcement learning (RL)-based adaptive S-surface controller for AUVs. Specifically, LLMs are introduced for the joint optimization of controller parameters and reward functions in RL training. Using multi-modal and structured explicit task feedback, LLMs enable joint adjustments, balance multiple objectives, and enhance task-oriented performance and adaptability. In the proposed controller, the RL policy focuses on upper-level tasks, outputting task-oriented high-level commands that the S-surface controller then converts into control signals, ensuring cancellation of nonlinear effects and unpredictable external disturbances in extreme sea conditions. Under extreme sea conditions involving complex terrain, waves, and currents, the proposed controller demonstrates superior performance and adaptability in high-level tasks such as underwater target tracking and data collection, outperforming traditional PID and SMC controllers.