As unmanned systems such as Unmanned Aerial Vehicles (UAVs) and Unmanned Ground Vehicles (UGVs) become increasingly important to applications like urban sensing and emergency response, efficiently recruiting these autonomous devices to perform time-sensitive tasks has become a critical challenge. This paper presents MPBS (Mobility-aware Prediction and Behavior-based Scheduling), a scalable task recruitment framework that treats each device as a recruitable "user". MPBS integrates three key modules: a behavior-aware KNN classifier, a time-varying Markov prediction model for forecasting device mobility, and a dynamic priority scheduling mechanism that considers task urgency and base station performance. By combining behavioral classification with spatiotemporal prediction, MPBS adaptively assigns tasks to the most suitable devices in real time. Experimental evaluations on the real-world GeoLife dataset show that MPBS significantly improves task completion efficiency and resource utilization. The proposed framework offers a predictive, behavior-aware solution for intelligent and collaborative scheduling in unmanned systems.