This paper presents a decentralized, online planning approach for scalable maneuver planning for large constellations. While decentralized, rule-based strategies have facilitated efficient scaling, optimal decision-making algorithms for satellite maneuvers remain underexplored. As commercial satellite constellations grow, there are benefits of online maneuver planning, such as using real-time trajectory predictions to improve state knowledge, thereby reducing maneuver frequency and conserving fuel. We address this gap in the research by treating the satellite maneuver planning problem as a Markov decision process (MDP). This approach enables the generation of optimal maneuver policies online with low computational cost. This formulation is applied to the low Earth orbit collision avoidance problem, considering the problem of an active spacecraft deciding to maneuver to avoid a non-maneuverable object. We test the policies we generate in a simulated low Earth orbit environment, and compare the results to traditional rule-based collision avoidance techniques.