Autonomous driving has attracted great interest due to its potential capability in full-unsupervised driving. Model-based and learning-based methods are widely used in autonomous driving. Model-based methods rely on pre-defined models of the environment and may struggle with unforeseen events. Proximal policy optimization (PPO), an advanced learning-based method, can adapt to the above limits by learning from interactions with the environment. However, existing PPO faces challenges with poor training results, and low training efficiency in long sequences. Moreover, the poor training results are equivalent to collisions in driving tasks. To solve these issues, this paper develops an improved PPO by introducing the risk-aware mechanism, a risk-attention decision network, a balanced reward function, and a safety-assisted mechanism. The risk-aware mechanism focuses on highlighting areas with potential collisions, facilitating safe-driving learning of the PPO. The balanced reward function adjusts rewards based on the number of surrounding vehicles, promoting efficient exploration of the control strategy during training. Additionally, the risk-attention network enhances the PPO to hold channel and spatial attention for the high-risk areas of input images. Moreover, the safety-assisted mechanism supervises and prevents the actions with risks of collisions during the lane keeping and lane changing. Simulation results on a physical engine demonstrate that the proposed algorithm outperforms benchmark algorithms in collision avoidance, achieving higher peak reward with less training time, and shorter driving time remaining on the risky areas among multiple testing traffic flow scenarios.