In this paper we present the implementation of a Control Barrier Function (CBF) using a quadratic program (QP) formulation that provides obstacle avoidance for a robotic manipulator arm system. CBF is a control technique that has emerged and developed over the past decade and has been extensively explored in the literature on its mathematical foundations, proof of set invariance and potential applications for a variety of safety-critical control systems. In this work we will look at the design of CBF for the robotic manipulator obstacle avoidance, discuss the selection of the CBF parameters and present a Reinforcement Learning (RL) scheme to assist with finding parameters values that provide the most efficient trajectory to successfully avoid different sized obstacles. We then create a data-set across a range of scenarios used to train a Neural-Network (NN) model that can be used within the control scheme to allow the system to efficiently adapt to different obstacle scenarios. Computer simulations (based on Matlab/Simulink) demonstrate the effectiveness of the proposed algorithm.