Mapping and localization are crucial problems in robotics and autonomous driving. Recent advances in 3D Gaussian Splatting (3DGS) have enabled precise 3D mapping and scene understanding by rendering photo-realistic images. However, existing 3DGS methods often struggle to accurately reconstruct a 3D map that reflects the actual scale and geometry of the real world, which degrades localization performance. To address these limitations, we propose a novel 3DGS method called Geometry-Aware Gaussian Splatting (GeomGS). This method fully integrates LiDAR data into 3D Gaussian primitives via a probabilistic approach, as opposed to approaches that only use LiDAR as initial points or introduce simple constraints for Gaussian points. To this end, we introduce a Geometric Confidence Score (GCS), which identifies the structural reliability of each Gaussian point. The GCS is optimized simultaneously with Gaussians under probabilistic distance constraints to construct a precise structure. Furthermore, we propose a novel localization method that fully utilizes both the geometric and photometric properties of GeomGS. Our GeomGS demonstrates state-of-the-art geometric and localization performance across several benchmarks, while also improving photometric performance.