Autonomous vehicles hold great promise for reducing traffic fatalities and improving transportation efficiency, yet their widespread adoption hinges on embedding credible and transparent ethical reasoning into routine and emergency maneuvers, particularly to protect vulnerable road users (VRUs) such as pedestrians and cyclists. Here, we present a hierarchical Safe Reinforcement Learning (Safe RL) framework that augments standard driving objectives with ethics-aware cost signals. At the decision level, a Safe RL agent is trained using a composite ethical risk cost, combining collision probability and harm severity, to generate high-level motion targets. A dynamic, risk-sensitive Prioritized Experience Replay mechanism amplifies learning from rare but critical, high-risk events. At the execution level, polynomial path planning coupled with Proportional-Integral-Derivative (PID) and Stanley controllers translates these targets into smooth, feasible trajectories, ensuring both accuracy and comfort. We train and validate our approach on closed-loop simulation environments derived from large-scale, real-world traffic datasets encompassing diverse vehicles, cyclists, and pedestrians, and demonstrate that it outperforms baseline methods in reducing risk to others while maintaining ego performance and comfort. This work provides a reproducible benchmark for Safe RL with explicitly ethics-aware objectives in human-mixed traffic scenarios. Our results highlight the potential of combining formal control theory and data-driven learning to advance ethically accountable autonomy that explicitly protects those most at risk in urban traffic environments. Across two interactive benchmarks and five random seeds, our policy decreases conflict frequency by 25-45% compared to matched task successes while maintaining comfort metrics within 5%.