LiDAR semantic segmentation frameworks predominantly use geometry-based features to differentiate objects within a scan. Although these methods excel in scenarios with clear boundaries and distinct shapes, their performance declines in environments where boundaries are indistinct, particularly in off-road contexts. To address this issue, recent advances in 3D segmentation algorithms have aimed to leverage raw LiDAR intensity readings to improve prediction precision. However, despite these advances, existing learning-based models face challenges in linking the complex interactions between raw intensity and variables such as distance, incidence angle, material reflectivity, and atmospheric conditions. Building upon our previous work, this paper explores the advantages of employing calibrated intensity (also referred to as reflectivity) within learning-based LiDAR semantic segmentation frameworks. We start by demonstrating that adding reflectivity as input enhances the LiDAR semantic segmentation model by providing a better data representation. Extensive experimentation with the Rellis-3d off-road dataset shows that replacing intensity with reflectivity results in a 4\% improvement in mean Intersection over Union (mIoU) for off-road scenarios. We demonstrate the potential benefits of using calibrated intensity for semantic segmentation in urban environments (SemanticKITTI) and for cross-sensor domain adaptation. Additionally, we tested the Segment Anything Model (SAM) using reflectivity as input, resulting in improved segmentation masks for LiDAR images.