Accurate forecasting of future solar irradiance is essential for the effective control of solar thermal power plants. Although various kriging-based methods have been proposed to address the prediction problem, these methods typically do not provide an appropriate sampling strategy to dynamically position mobile sensors for optimizing prediction accuracy in real time, which is critical for achieving accurate forecasts with a minimal number of sensors. This paper introduces a dissimilarity map derived from a kriging model and proposes a persistent coverage control algorithm that effectively guides agents toward regions where additional observations are required to improve prediction performance. By means of experiments using mobile robots, the proposed approach was shown to obtain more accurate predictions than the considered baselines under various emulated irradiance fields.