Mechanical search (MS) in cluttered environments remains a significant challenge for autonomous manipulators, requiring long-horizon planning and robust state estimation under occlusions and partial observability. In this work, we introduce XPG-RL, a reinforcement learning framework that enables agents to efficiently perform MS tasks through explainable, priority-guided decision-making based on raw sensory inputs. XPG-RL integrates a task-driven action prioritization mechanism with a learned context-aware switching strategy that dynamically selects from a discrete set of action primitives such as target grasping, occlusion removal, and viewpoint adjustment. Within this strategy, a policy is optimized to output adaptive threshold values that govern the discrete selection among action primitives. The perception module fuses RGB-D inputs with semantic and geometric features to produce a structured scene representation for downstream decision-making. Extensive experiments in both simulation and real-world settings demonstrate that XPG-RL consistently outperforms baseline methods in task success rates and motion efficiency, achieving up to 4.5$\times$ higher efficiency in long-horizon tasks. These results underscore the benefits of integrating domain knowledge with learnable decision-making policies for robust and efficient robotic manipulation. The project page for XPG-RL is https://yitingzhang1997.github.io/xpgrl/.