As modern computing advances, new interaction paradigms have emerged, particularly in Augmented Reality (AR), which overlays virtual interfaces onto physical objects. This evolution poses challenges in machine perception, especially for tasks like 3D object pose estimation in complex, dynamic environments. Our project addresses critical issues in human-robot interaction within mobile AR, focusing on non-intrusive, spatially aware interfaces. We present URSA, an LLM-driven immersive AR system developed for NASA's 2023-2024 SUITS challenge, targeting future spaceflight needs such as the Artemis missions. URSA integrates three core technologies: a head-mounted AR device (e.g., HoloLens) for intuitive visual feedback, voice control powered by large language models for hands-free interaction, and robot tracking algorithms that enable accurate 3D localization in dynamic settings. To enhance precision, we leverage digital twin localization technologies, using datasets like DTTD-Mobile and specialized hardware such as the ZED2 camera for real-world tracking under noise and occlusion. Our system enables real-time robot control and monitoring via an AR interface, even in the absence of ground-truth sensors--vital for hazardous or remote operations. Key contributions include: (1) a non-intrusive AR interface with LLM-based voice input; (2) a ZED2-based dataset tailored for non-rigid robotic bodies; (3) a Local Mission Control Console (LMCC) for mission visualization; (4) a transformer-based 6DoF pose estimator (DTTDNet) optimized for depth fusion and real-time tracking; and (5) end-to-end integration for astronaut mission support. This work advances digital twin applications in robotics, offering scalable solutions for both aerospace and industrial domains.